Tailoring Magnetic Properties of Cubic Spinel Ferrite Core–Shell Nanoparticles for Magnetoresistive Engineering
Main Article Content
Abstract
Magnetite nanoparticles with a cobalt ferrite shell provide the opportunity to obtain a tunneling magnetoresistance structure and offer an additional degree of freedom in shaping the magnetoresistive characteristics. In order to investigate the effect of the relative fractions of the shell on magnetic and magnetoresistive properties, we have prepared (by chemical co-precipitation) a bi-magnetic (soft/hard) core–shell Fe3O4/CoFe2O4 nanoparticle system (with diameters of a few nm). The structural, magnetic, and electric transport properties of the as-prepared core precursor, core–shell nanoparticles, and sintered powder were determined. It was found that the obtained particles, which are few nanometers in size, have the desired single-crystalline spinel structure with a core–shell architecture and the expected magnetic properties associated with core–shell interactions. Sintering leads to more complex magnetic behavior and tunneling conductance.
Article Details

This work is licensed under a Creative Commons Attribution 4.0 International License.
References
J.-B. Moussy, J. Phys. D Appl. Phys. 46, 143001 (2013), https://doi.org/10.1088/0022-3727/46/14/143001
R. von Helmolt, J. Wecker, B. Holzapfel, L. Schultz, K. Samwer, Phys. Rev. Lett. 71, 2331 (1993), https://doi.org/10.1103/PhysRevLett.71.2331
J.S. Moodera, L.R. Kinder, T.M. Wong, R. Meservey, Phys. Rev. Lett. 74, 3273 (1995), https://doi.org/10.1103/PhysRevLett.74.3273
G.-X. Miao, M. Munzenberg, J.S. Moodera, Rep. Prog. Phys. 74, 036501 (2011), https://doi.org/10.1088/0034-4885/74/3/036501
B. Dieny, V.S. Speriosu, S.S.P. Parkin, B.A. Gurney, D.R. Wilhoit, D. Mauri, Phys. Rev. B 43, 1297(R) (1991), https://doi.org/10.1103/PhysRevB.43.1297
S. Yuasa, T. Nagahama, A. Fukushima, Y. Suzuki, K. Ando, Nat. Mater. 3, 868 (2004), https://doi.org/10.1038/nmat1257
D.D. Djayaprawira, K. Tsunekawa, M. Nagai, H. Maehara, S. Yamagata, N. Watanabe, S. Yuasa, Y. Suzuki, K. Ando, Appl. Phys. Lett. 86, 092502 (2005), https://doi.org/10.1063/1.1871344
F. Fabris, E. Lima Jr., C. Quinteros et al., Phys. Rev. Appl. 11, 054089 (2019), https://doi.org/10.1103/PhysRevApplied.11.054089
R.A. de Groot, F.M. Mueller, P.G. van Engen, K.H.J. Buschow, Phys. Rev. Lett. 50, 2024 (1983), https://doi.org/10.1103/PhysRevLett.50.2024
W.E. Pickett, J.S. Moodera, Phys. Today 54, 39 (2001), https://doi.org/10.1063/1.1381101
H.C. Kandpal, G.H. Fecher, C. Felser, J. Phys. D Appl. Phys. 40, 1507 (2007), https://doi.org/10.1088/0022-3727/40/6/S01
J.M.D. Coey, A.E. Berkowitz, Ll. Balcells, F.F. Putris, A. Barry, Phys. Rev. Lett. 80, 3815 (1998), https://doi.org/10.1103/PhysRevLett.80.3815
J.M.D. Coey, A.E. Berkowitz, Ll. Balcells, F.F. Putris, F.T. Parker, Appl. Phys. Lett. 72, 734 (1998), https://doi.org/10.1063/1.120859
J.M.D. Coey, J. Appl. Phys. 85, 5576 (1999), https://doi.org/10.1063/1.369899
X.W. Li, A. Gupta, G. Xiao, G.Q. Gong, Appl. Phys. Lett. 71, 1124 (1997), https://doi.org/10.1063/1.119747
H.Y. Hwang, S.W. Cheong, N.P. Ong, B. Batlogg, Phys. Rev. Lett. 77, 2041 (1996), https://doi.org/10.1103/PhysRevLett.77.2041
A.E. Berkowitz, J.R. Mitchell, M.J. Carey, A.P. Young, S. Zhang, F.E. Spada, F.T. Parker, A. Hutten, G. Thomas, Phys. Rev. Lett. 68, 3745 (1992), https://doi.org/10.1103/PhysRevLett.68.3745
J.Q. Xiao, J.S. Jiang, C.L. Chien, Phys. Rev. Lett. 68, 3749 (1992), https://doi.org/10.1103/PhysRevLett.68.3749
B.H. Zhou, J.D. Rinehart, ACS Cent. Sci. 4, 1222 (2018), https://doi.org/10.1021/acscentsci.8b00399
D.D. Sarma, S. Ray, K. Tanaka, M. Kobayashi, A. Fujimori, P. Sanyal, H.R. Krishnamurthy, C. Dasgupta, Phys. Rev. Lett. 98, 157205 (2007), https://doi.org/10.1103/PhysRevLett.98.157205
S. Jana, S. Middey, S. Ray, J. Phys. Condens. Matter. 22, 346004 (2010), https://doi.org/10.1088/0953-8984/22/34/346004
S. Ray, S. Middey, S. Jana, A. Banerjee, P. Sanyal, R. Rawat, L. Gregoratti, D.D. Sarma, Europhys. Lett. 94, 47007 (2011), https://doi.org/10.1209/0295-5075/94/47007
P.A. Kumar, S. Ray, S. Chakraverty, D.D. Sarma, Appl. Phys. Lett. 103, 102406 (2013), https://doi.org/10.1063/1.4819956
A. López-Ortega, M. Estrader, G. Salazar-Alvarez, A.G. Roca, J. Nogues, Phys. Rep. 553, 1 (2015), https://doi.org/10.1016/j.physrep.2014.09.007
H. Liu, E.Y. Jiang, H.L. Bai, R.K. Zheng, H.L. Wei, X.X. Zhang, Appl. Phys. Lett. 83, 3531 (2003), https://doi.org/10.1063/1.1622440
M. Fonin, Y. Dedkov, C. Konig, G. Guntherodt, U. Rudiger, J. Mayer, D. Vyalikh, S. Molodtsov, in: Advances in Solid State Physics, Vol. 43, Ed. B. Kramer, Springer, Berlin 2003, p. 487, https://doi.org/10.1007/978-3-540-44838-9_35
A.V. Ramos, M.J. Guittet, J.B. Moussy, R. Mattana, C. Deranlot, F. Petroff, C. Gatel, Appl. Phys. Lett. 91, 122107 (2007), https://doi.org/10.1063/1.2787880
S. Matzen, J.B. Moussy, R. Mattana, K. Bouzehouane, C. Deranlot, F. Petroff, Appl. Phys. Lett. 101, 042409 (2012), https://doi.org/10.1063/1.4738790
A.V. Ramos, T.S. Santos, G.X. Miao, M.J. Guittet, J.B. Moussy, J.S. Moodera, Phys. Rev. B 78, 180402(R) (2008), https://doi.org/10.1103/PhysRevB.78.180402
R.H. Kodama, J. Magn. Magn. Mater. 200, 359 (1999), https://doi.org/10.1016/S0304-8853(99)00347-9
A. Houbi, Z.A. Aldashevich, Y. Atassi, Z.B. Telmanovna, M. Saule, K. Kubanych, J. Magn. Magn. Mater. 529, 167839 (2021), https://doi.org/10.1016/j.jmmm.2021.167839
Z. Ma, J. Mohapatra, K. Wei, J.P. Liu, S. Sun, Chem. Rev. 123, 3904 (2023), https://doi.org/10.1021/acs.chemrev.1c00860
A. Mitra, J. Mohapatra, M. Aslam, Mater. Res. Express 11, 022002 (2024), https://doi.org/10.1088/2053-1591/ad2a84
Ö. Özdemir, Geophys. J. Int. 141, 351 (2000), https://doi.org/10.1046/j.1365-246x.2000.00081.x
O.V. Yelenich, S.O. Solopan, J.M. Greneche, A.G. Belous, Solid State Sci. 46, 19 (2015), https://doi.org/10.1016/j.solidstatesciences.2015.05.011
F. Bosi, U. Halenius, H. Skogby, Am. Mineral. 94, 181 (2009), https://doi.org/10.2138/am.2009.3002
H.-S. Shin, J. Korean Ceram. Soc. 35, 1113 (1998)]
T.A.S. Ferreira, J.C. Waerenborgh, M.H.R.M. Mendonca, M.R. Nunes, F.M. Costa, Solid State Sci. 5, 383 (2003), https://doi.org/10.1016/S1293-2558(03)00011-6
R. Frison, G. Cernuto, A. Cervellino, O. Zaharko, G.M. Colonna, A. Guagliardi, N. Masciocchi, Chem. Mater. 25, 4820 (2013), https://doi.org/10.1021/cm403360f
A. Cervellino, R. Frison, G. Cernuto, A. Guagliardi, N. Masciocchi, J. Appl. Cryst. 47, 1755 (2014), https://doi.org/10.1107/S1600576714019840
Q. Song, Z.J. Zhang, J. Am. Chem. Soc. 134, 10182 (2012), https://doi.org/10.1021/ja302856z
O. Masala, D. Hoffman, N. Sundaram, K. Page, T. Proffen, G. Lawes, R. Seshadri, Solid State Sci. 8, 1015 (2006), https://doi.org/10.1016/j.solidstatesciences.2006.04.014
B. Issa, I.M. Obaidat, B.A. Albiss, Y. Haik, Int. J. Mol. Sci. 14, 21266 (2013), https://doi.org/10.3390/ijms141121266
A.H. Lu, E.L. Salabas, F. Schüth, Angew. Chem. Int. Ed. 46, 1222 (2007), https://doi.org/10.1002/anie.200602866
S.O. Solopan, N. Nedelko, S. Lewińska, A. Ślawska-Waniewska, V.O. Zamorskyi, A.I. Tovstolytkin, A.G. Belous, J. Alloys Compd. 788, 1203 (2019), https://doi.org/10.1016/j.jallcom.2019.02.276
D. Polishchuk, N. Nedelko, S. Solopan, A. Ślawska-Waniewska, V. Zamorskyi, A. Tovstolytkin, A. Belous, Nanoscale Res. Lett. 13, 67 (2018), https://doi.org/10.1186/s11671-018-2481-x
E. du Tremolet de Lacheisserie, Magnetostriction: Theory and Applications of Magnetoelasticity, CRC Press, Boca Raton (FL) 1993
A. López-Ortega, M. Estrader, G. Salazar-Alvarez et al., Nanoscale 4, 5138 (2012), https://doi.org/10.1039/C2NR30986F
G. Salazar-Alvarez, J. Sort, A. Uheida, M. Muhammed, S. Surinach, M.D. Baro, J. Nogues, J. Mater. Chem. 17, 322 (2007), https://doi.org/10.1039/B613026G
J.M.D. Coey, Magnetism and Magnetic Materials , Cambridge University Press, Cambridge 2010
P. Sheng, Philos. Mag. B 65, 357 (1992), https://doi.org/10.1080/13642819208207638
P. Sheng, Phys. Rev. B 21, 2180 (1980), https://doi.org/10.1103/PhysRevB.21.2180
C. Park, Y. Peng, J.G. Zhu, D.E. Laughlin, R.M. White, J. Appl. Phys. 97, 10C303 (2005), https://doi.org/10.1063/1.1847853
P. Sheng, B. Abeles, Y. Arie, Phys. Rev. Lett. 31, 44 (1973), https://doi.org/10.1103/PhysRevLett.31.44
H. Liu, E.Y. Jiang, H.L. Bai, R.K. Zheng, X.X. Zhang, J. Phys. D Appl. Phys. 36, 2950 (2003), https://doi.org/10.1088/0022-3727/36/23/013